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2014/06/20

Nature Materials contents: July 2014 Volume 13 Number 7 pp 663-756

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TABLE OF CONTENTS

July 2014 Volume 13, Issue 7

Editorial
Research Highlights
News and Views
Letters
Articles
Corrigendum
Erratum

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Editorial

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Debated waters   p663
doi:10.1038/nmat4029
New experiments and computer simulations on how water behaves when it is supercooled are poised to rekindle long-standing debates.

Research Highlights

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Durable delivery | Wide angle vision | The importance of coherence | E-cadherin-guided migration | 3D skyrmion imaging


News and Views

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Cuprate superconductors: Dynamic stabilization?   pp665 - 666
N. Peter Armitage
doi:10.1038/nmat3995
Enhancing the temperature at which superconductivity is observed is a long-standing objective for materials scientists. Recent tantalizing experiments suggest a possible route for achieving this.

See also: Article by Hu et al.

Nanoscale friction: Sliding charges   pp666 - 668
Robert Szoszkiewicz and Elisa Riedo
doi:10.1038/nmat4020
In contrast to the ultralow friction that exists between carbon layers in multiwalled carbon nanotubes, multiwalled boron nitride nanotubes are found to exhibit ultrahigh interlayer friction as a result of their ionic character.

See also: Letter by Niguès et al.

Material witness: The clean air act   p668
Philip Ball
doi:10.1038/nmat4016

Organic polaritons: Long-distance relationships   pp669 - 670
Russell J. Holmes
doi:10.1038/nmat3986
By embedding organic dyes in a suitably designed optical microcavity it is possible to strongly mix light and matter excitations, forming states known as microcavity polaritons. These hybrid light–matter states are used to demonstrate energy transfer between organic molecules over long distances.

See also: Article by Coles et al.

Crystal nucleation: Zeroing in on ice   pp670 - 671
Ben Slater and David Quigley
doi:10.1038/nmat4017
Computer simulations show that cubic and hexagonal ices nucleate through the formation of a tetragonal metastable ice phase.

See also: Article by Russo et al.

Supercooled water: Continuous trends   pp671 - 673
Alan K. Soper
doi:10.1038/nmat4019
X-ray scattering measurements of liquid water down to temperatures at which it spontaneously converts to ice show no signs of the much debated transition from high-density to low-density structural order.

Supercooled water: Two phases?   pp673 - 675
C. Austen Angell
doi:10.1038/nmat4022
Simulations of a well-studied model of water provide strong support for the coexistence of two distinct metastable liquid-water phases, a long-debated possibility that experiments on supercooled water at negative pressures may be able to confirm.

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Letters

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A stable three-dimensional topological Dirac semimetal Cd3As2   pp677 - 681
Z. K. Liu, J. Jiang, B. Zhou, Z. J. Wang, Y. Zhang, H. M. Weng, D. Prabhakaran, S-K. Mo, H. Peng, P. Dudin, T. Kim, M. Hoesch, Z. Fang, X. Dai, Z. X. Shen, D. L. Feng, Z. Hussain and Y. L. Chen
doi:10.1038/nmat3990
A state of matter known as a three-dimensional Dirac semimetal has latterly garnered significant theoretical and experimental attention. Using angle-resolved photoelectron spectroscopy, it is shown that Cd3As2 is an experimental realization of a three-dimensional Dirac semimetal that is stable at ambient conditions.

Intense low-energy ferromagnetic fluctuations in the antiferromagnetic heavy-fermion metal CeB6   pp682 - 687
Hoyoung Jang, G. Friemel, J. Ollivier, A. V. Dukhnenko, N. Yu. Shitsevalova, V. B. Filipov, B. Keimer and D. S. Inosov
doi:10.1038/nmat3976
Cerium hexaboride is a canonical heavy-fermion system that has come under scrutiny because of its so-called hidden order phase. Now, detailed inelastic neutron scattering experiments reveal an intense ferromagnetic mode, thus overturning the generally accepted view that antiferromagnetic interactions dominate the low-temperature behaviour of this system.

Ultrahigh interlayer friction in multiwalled boron nitride nanotubes   pp688 - 693
A. Niguès, A. Siria, P. Vincent, P. Poncharal and L. Bocquet
doi:10.1038/nmat3985
Carbon nanotubes (CNTs) and boron nitride nanotubes (BNNTs) have similar surface crystallography and mechanical properties. It is now shown that the interlayer sliding friction in multilayer CNTs and BNNTs is, however, different: whereas the telescopic sliding of semi-metallic multiwalled CNTs is known to be vanishingly small, multiwalled insulating BNNTs exhibit ultrahigh interlayer friction that is proportional to the contact area—a result ascribed to the ionic character of boron nitride.

See also: News and Views by Szoszkiewicz & Riedo

Electrostatic control of block copolymer morphology   pp694 - 698
Charles E. Sing, Jos W. Zwanikken and Monica Olvera de la Cruz
doi:10.1038/nmat4001
Block copolymers can self-assemble into nanostructures that simultaneously facilitate ion transport and provide mechanical stability. Highly asymmetric charge cohesion effects are now shown to induce the formation of nanostructures with percolated phases desired for ion transport. This strategy could lead to the design of enhanced battery electrolyte materials.

Articles

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Magnetization switching through giant spin–orbit torque in a magnetically doped topological insulator heterostructure   pp699 - 704
Yabin Fan, Pramey Upadhyaya, Xufeng Kou, Murong Lang, So Takei, Zhenxing Wang, Jianshi Tang, Liang He, Li-Te Chang, Mohammad Montazeri, Guoqiang Yu, Wanjun Jiang, Tianxiao Nie, Robert N. Schwartz, Yaroslav Tserkovnyak and Kang L. Wang
doi:10.1038/nmat3973
Heterostructures consisting of ferromagnets and heavy metals have become a focus of interest because their strong spin–orbit coupling allows for efficient current-induced magnetization switching phenomena. Now, a magnetically doped topological insulator bilayer is shown to display a range of appealing characteristics for current-induced magnetization switching, including a significantly enhanced efficiency.

Optically enhanced coherent transport in YBa2Cu3O6.5 by ultrafast redistribution of interlayer coupling   pp705 - 711
W. Hu, S. Kaiser, D. Nicoletti, C. R. Hunt, I. Gierz, M. C. Hoffmann, M. Le Tacon, T. Loew, B. Keimer and A. Cavalleri
doi:10.1038/nmat3963
Mode-selective vibrational excitations can be used to transiently induce a range of phenomena in strongly correlated states of matter. It is now shown that by exciting apical oxygen distortions in the cuprate system YBa2Cu3O6.5, an unusual photoconductive effect is induced both at low and at high temperatures.

See also: News and Views by Armitage

Polariton-mediated energy transfer between organic dyes in a strongly coupled optical microcavity   pp712 - 719
David M. Coles, Niccolo Somaschi, Paolo Michetti, Caspar Clark, Pavlos G. Lagoudakis, Pavlos G. Savvidis and David G. Lidzey
doi:10.1038/nmat3950
The energy interaction between different exciton species is affected by the optical environment in which they are embedded. It is now shown that mixed exciton–polariton states in strongly coupled microcavities can facilitate energy transfer between organic dyes at length scales greater than the Förster transfer radius.

See also: News and Views by Holmes

Engineering of light confinement in strongly scattering disordered media   pp720 - 725
Francesco Riboli, Niccolò Caselli, Silvia Vignolini, Francesca Intonti, Kevin Vynck, Pierre Barthelemy, Annamaria Gerardino, Laurent Balet, Lianhe H. Li, Andrea Fiore, Massimo Gurioli and Diederik S. Wiersma
doi:10.1038/nmat3966
Disordered photonic materials have the ability to control the flow of light through random multiple scattering. This has the drawback of randomizing both the direction and phase of the propagating light. Now, confined and interacting light modes are demonstrated for a two-dimensional disordered photonic structure.

Anion charge storage through oxygen intercalation in LaMnO3 perovskite pseudocapacitor electrodes   pp726 - 732
J. Tyler Mefford, William G. Hardin, Sheng Dai, Keith P. Johnston and Keith J. Stevenson
doi:10.1038/nmat4000
Perovskite oxides have attracted significant attention as energy conversion materials owing to their unique physical and electronic properties. Anion-based intercalation pseudocapacitance as well as oxygen intercalation in a nanostructured lanthanum-based perovskite (LaMnO3) have now been exploited for fast energy storage.

New metastable form of ice and its role in the homogeneous crystallization of water   pp733 - 739
John Russo, Flavio Romano and Hajime Tanaka
doi:10.1038/nmat3977
At sufficiently low temperature, liquid water crystallizes into ices with cubic or hexagonal symmetry. A simulation study now shows that the nucleation of water into atomic stackings of cubic and hexagonal ices occurs through a metastable precursor phase with tetragonal symmetry, and that this scenario provides an explanation for the unusual pressure dependence of water’s homogeneous crystal-nucleation temperature.

See also: News and Views by Slater & Quigley

In situ micropillar compression reveals superior strength and ductility but an absence of damage in lamellar bone   pp740 - 747
Jakob Schwiedrzik, Rejin Raghavan, Alexander Bürki, Victor LeNader, Uwe Wolfram, Johann Michler and Philippe Zysset
doi:10.1038/nmat3959
The fracture behaviour of micro- and macroscale bone is shown to be different. In situ micropillar compression experiments on ovine bone demonstrate that microscale lamellar bone is strong and ductile, and shows no damage, whereas on the macroscale, bone shows little ductility and fails in a quasi-brittle manner.

Bacteria-instructed synthesis of polymers for self-selective microbial binding and labelling   pp748 - 755
E. Peter Magennis, Francisco Fernandez-Trillo, Cheng Sui, Sebastian G. Spain, David J. Bradshaw, David Churchley, Giuseppe Mantovani, Klaus Winzer and Cameron Alexander
doi:10.1038/nmat3949
Enzymes involved in copper metabolism and residing within bacterial outer layers are used to polymerize monomers bound to the bacterial cell surface. The composition of the polymers is affected by templating processes and hence the polymers are specific binding agents for the bacteria on which they are grown.

Corrigendum

Top

Corrigendum: Singular robust room-temperature spin response from topological Dirac fermions   p756
Lukas Zhao, Haiming Deng, Inna Korzhovska, Zhiyi Chen, Marcin Konczykowski, Andrzej Hruban, Vadim Oganesyan and Lia Krusin-Elbaum
doi:10.1038/nmat4011

Erratum

Top

Erratum: Materials as stem cell regulators   p756
William L. Murphy, Todd C. McDevitt and Adam J. Engler
doi:10.1038/nmat4013

Top
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